生物降解油浸绝缘纸特征产物及微观结构研究
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TM 216

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Study on Characteristic Products and Microstructure of Biodegradable Oil-mpregnated Insulation Paper
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    摘要:

    为研究微生物对油浸绝缘纸降解,文中将试样油纸质量比按10∶1制样,采取自然污染、人工接种、高温杀菌方法预处理对照试样,试样3~4中加入金属铝,试样5中加入金属铜,选择微生物最适宜生长环境温度为15~35 ℃下进行生物降解试验。通过高效液相色谱仪、气相色谱仪、扫描电子显微镜等仪器,检测分析微生物降解油浸绝缘纸产物及气体产物含量变化趋势并观察试验前后绝缘纸纤维素微观结构变化。试验结果表明,经微生物降解后,产生了糠醛、CO和CO2特征产物,绝缘纸纤维素结构破坏。CO和CO2含量随微生物降解先增后减,然后再增加,最后趋于稳定;绝缘纸纤维素微观形貌发生了改变,纤维素结晶区纤维表面变粗糙、部分松散或断裂,非结晶区出现小的孔隙,结晶区与非结晶区连接不够紧密。降解特征产物及其气体产物变化特征为辨识非运行电力设备绝缘纸是否发生微生物污染提供重要参考依据。

    Abstract:

    In order to study the degradation of oil-mpregnated insulation paper by microorganisms, the mass ratio of oil-aper sample is about 10∶1, and the comparative samples are pretreated by natural pollination, artificial inoculation and high temperature sterilization. Metal aluminum is added into samples 3 and 4, and metal copper is added into sample 5. The biodegradation test is carried out at 15~35 ℃ which is the most suitable ambient temperature. The products of biodegradable oil-mpregnated insulation paper and the change trend of gas content are analyzed by high performance liquid chromatography, gas chromatography and other instruments, and the changes of microstructure of oil-mpregnated insulation paper before and after the test are observed by scanning electron microscope (SEM). The test results show that after the biodegradation, characteristic products are generated such as furfural, CO and CO2, but the structure of cellulose of insulation paper has been damaged. The contents of CO and CO2 increases first then decreases, and then increases, and finally it tends towards stability with microbial degradation. The SEM shows that the crystals and amorphous structures of cellulose have changed, the crystalline region of cellulose surface becomes rough, loose and fractured, the amorphous region occurs small pores, and the crystalline region is not closely connected with the amorphous region. Characteristic products of degradation and the variation characteristics of their gas product are important reference basis for distinguishing whether microbial contamination occurs in insulation paper of non-perating power equipment.

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  • 在线发布日期: 2022-11-02
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